Hirako Shinji & Shiba Kaien
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Summary
On a bright autumn afternoon, a series of events take place:
1) In an outer district of Rukongai, eight captains and lieutenants are Hollowfied, saved, and brought back to the Fourth Division for treatment under the combined protection of Urahara Kisuke and Unohana Retsu.
2) Aizen Sousuke attempts to stage a coup against the Gotei 13 and fails. Very badly.
And 3) Shiba Kaien suddenly reveals never-before-observed Zanpakutou abilities, and his reiatsu levels absolutely skyrocket, all before single-handedly saving the Shinigami from Aizen's machinations, mental manipulations, and probably a drawn-out civil war just to round it out.
All of these events are far more intertwined than anyone will ever understand, but Shinji tries anyway.